On the Active Agents in Luminescent Calcites, Aragonites, and Dolomites

T. Tanaka

doi:10.1364/JOSA.8.000411

On the Active Agents in Luminescent Calcites, Aragonites, and Dolomites

T. Tanaka

Journal of the Optical Society of America
Vol. 8,
Issue 3,
pp. 411-418
(1924)
•https://doi.org/10.1364/JOSA.8.000411

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T. Tanaka, "On the Active Agents in Luminescent Calcites, Aragonites, and Dolomites," J. Opt. Soc. Am. 8, 411-418 (1924)

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Substance	Active Agents	Bands identified.

Calcite I	Mn(12)	5910, 5893(6), 5831, 5795(4), 5754, 5690(1), 5617(8), 5573(4), 5524(5), 5469(0), 5423, 5367(5).
Calcite I	Dy(3)	5872(3), 5719(0), 5659(61).

Calcite II	Mn(7)	5855, 5896, 6794, 5523(5), 5489(8), 5432, 5423.
	Yt(6)	6133(5), 5817, 5762(3), 5669(0), 5599, 5531.
	Tl(3)	6075(3), 6010, 5710(1).

Calcite III	Mn(9)	5897(6), 5855, 5831, 5793(4), 5742(1), 5681(2), 5632(1), 5558(9), 5524(5).
Calcite III	Dy(4)	5871(3), 5781(0), 5720, 5603.

Calcite IV	Mn(10)	6161(58), 6127(31), 5896, 5853(5), 5834(1), 5794, 5755(4), 5740(1), 5681(2), 5618.
	Yt(6)	6053, 6017(6), 5972, 5929, 5820(17), 5670,
	Dy(4)	5938(6), 5875(3), 5781(0), 5718(20).

Calcite V	Mn(11)	6202(3), 6157(8), 6130(1), 5977, 5910, 5893(6), 5830(1), 5794, 5741, 5689(1), 5616(8).
	Yt(4)	6104(5), 6053, 5929, 5669(0).
	Tl(3)	5948, 5771(69), 5710(1).
	Dy(1)	5873.

Calcite VI	Mn(12)	6031, 5977, 5973(4), 5910, 5830(1), 5795(4), 5755(4), 5739(41), 5692(1), 5680(2), 5631, 5559.
Calcite VI	Yb?(7)	5962(4), 5865(6), 5776, 5717(6), 5598(9), 5577, 5522.

Calcite VII	Mn(13)	6427, 6291(3), 6225(7), 6202(3), 6158, 6128(31), 6099(8), 5894(6), 5953(5), 5753(4), 5740(1), 5691, 5631.
	Dy(5)	6383(5), 6272(5), 6069(8), 5809(11), 5659(61).
	Sa(3)	6041, 6019(7), 5966.

Calcite VIII	Mn(9)	6426(7), 6361, 6286(9), 6129(31), 6044(6), 5981(77), 5898(6), 5853(3), 5683(2).
Calcite VIII	Yt(3)	6491, 6199(7), 5743(2).

Calcite IX	Mn(15)	6544, 6502, 6462(4), 6427, 6360(1), 6288(9), 6204(3), 6132, 6095(8), 5979(7), 5852(5), 5793(4), 5753(4), 5690(1), 5631.
Calcite IX	Yt(2)	6053, 5928(9).

Calcite X	Mn(19)	6545(4), 6464, 6426(7), 6360(1), 6225(7), 6201(3), 6159(8), 6129(31), 6099(8), 6048(6), 5980(77), 5973(4), 5909(10), 5794, 5752(4), 5680(2), 5630(1), 5575(4), 5523(5).
Calcite X	Dy(2)	6275, 5844(2).

Calcite XI	Mn(13)	6503(2), 6427, 6292(3), 6228(7), 6159(8), 6097(8), 6047(6), 5977, 5896, 5854(5), 5755(4), 5693(1), 5631.
Calcite XI	Dy(5)	6422, 6348, 6001, 5934(6), 5809(11).

Calcite XII	Mn(10)	6359(61), 6202(3), 6157(8), 6098, 5977, 5910, 5795(4), 5741, 5680(2), 5621(18).
Calcite XII	Sa(6)	6533(4), 6444(6), 6269, 6120(18), 6039(41), 5841.

Substance	Active Agents	Bands recognized

Crystalline Limestone I	Dy(11)	6100(1), 6001, 5907(5), 5873, 5810(1), 5780, 5749(50), 5720, 5690(1), 5660(1), 5632.
Crystalline Limestone I	Mn(7)	6048(6), 5978(7), 5895(6), 5855, 5752(4), 5559, 5430(2).
Red Band	Tl(4)	5951(48), 5884(7), 5711, 5602(0).
Blue Band	Dy(7)	4970, 4944(7); 4925, 4900(3), 4885(2), 4838(9), 4798(6),
	Mn(2)	5005, 4885(3).

Crystalline Limestone II	Mn(8)	5896, 5858(5), 5834(1), 5794; 5740(1), 5693(1), 5631, 5616(8).
	Dy(6)	5998(01), 5811, 5779(0), 5722(0), 5661, 5603.
	Tl(2)	5947(8), 5657(5).

Old Lime	Mn(12)	6361, 6288(9), 6228(7), 6158, 6099(8), 6048(6), 5974, 5911(0), 5752(4), 5691, 5628(1), 5574.
Old Lime	Dy(2)	5845(2), 5812(1).

Aragonite I	Mn(17)	6227, 6157(8), 6100(98), 6029(931), 5974, 5910, 5893(6), 5857(5), 5831, 5794, 5754, 5741, 5682, 5632(1), 5560(59), 5470, 5423.
Aragonite I	Sr(3)	5961(59), 5818(6), 5504(6).

Aragonite II	Sr(32)	5771(0), 5718(9), 5680, 5636, 5610, 5576(5), 5550, 5540, 5509(8), 5472, 5440(39), 5406, 5386(5), 5374(3), 5347(6), 5340(1), 5308(7), 5265(8), 5245(6), 5230(1), 5193, 5186(5), 5154(5), 5125, 5096, 5084, 5050(49), 5039(8), 5014, 5009(10), 4980, 4954.
Aragonite II	Cu(2)	5485, 5435.

Dolomite I	Dy(15)	6001, 5933(6), 5873, 5750, 5662(1), 5634(2), 5601(3), 5547, 5518(9), 5410, 5383(4), 5332, 5305(6), 5255, 5205.
Dolomite I	Mn(9)	5971(4), 5894(6), 5829(31), 5792(4), 5682, 5572(4), 5487(8), 5469(0), 5421(3).

Dolomite II	Mn(16)	6542(4), 6462(4), 6369, 6293, 6227, 6160(58), 6100(98), 5973(4), 5894(6), 5831, 5796(4), 5739(1), 5682, 5628(1), 5574, 5523(5).
Dolomite II	Yt(1)	6054(3).

Magnesite	Mn(10)	6543(4), 6461(4), 6290(3), 6206(3), 6131, 6046, 5979(7), 5910, 5855, 5794.
Magnesite	Dy(3)	6384(5), 6068, 5842.

Substance	Active Agents	Bands identified.

Calcite I	Mn(12)	5910, 5893(6), 5831, 5795(4), 5754, 5690(1), 5617(8), 5573(4), 5524(5), 5469(0), 5423, 5367(5).
Calcite I	Dy(3)	5872(3), 5719(0), 5659(61).

Calcite II	Mn(7)	5855, 5896, 6794, 5523(5), 5489(8), 5432, 5423.
	Yt(6)	6133(5), 5817, 5762(3), 5669(0), 5599, 5531.
	Tl(3)	6075(3), 6010, 5710(1).

Calcite III	Mn(9)	5897(6), 5855, 5831, 5793(4), 5742(1), 5681(2), 5632(1), 5558(9), 5524(5).
Calcite III	Dy(4)	5871(3), 5781(0), 5720, 5603.

Calcite IV	Mn(10)	6161(58), 6127(31), 5896, 5853(5), 5834(1), 5794, 5755(4), 5740(1), 5681(2), 5618.
	Yt(6)	6053, 6017(6), 5972, 5929, 5820(17), 5670,
	Dy(4)	5938(6), 5875(3), 5781(0), 5718(20).

Calcite V	Mn(11)	6202(3), 6157(8), 6130(1), 5977, 5910, 5893(6), 5830(1), 5794, 5741, 5689(1), 5616(8).
	Yt(4)	6104(5), 6053, 5929, 5669(0).
	Tl(3)	5948, 5771(69), 5710(1).
	Dy(1)	5873.

Calcite VI	Mn(12)	6031, 5977, 5973(4), 5910, 5830(1), 5795(4), 5755(4), 5739(41), 5692(1), 5680(2), 5631, 5559.
Calcite VI	Yb?(7)	5962(4), 5865(6), 5776, 5717(6), 5598(9), 5577, 5522.

Calcite VII	Mn(13)	6427, 6291(3), 6225(7), 6202(3), 6158, 6128(31), 6099(8), 5894(6), 5953(5), 5753(4), 5740(1), 5691, 5631.
	Dy(5)	6383(5), 6272(5), 6069(8), 5809(11), 5659(61).
	Sa(3)	6041, 6019(7), 5966.

Calcite VIII	Mn(9)	6426(7), 6361, 6286(9), 6129(31), 6044(6), 5981(77), 5898(6), 5853(3), 5683(2).
Calcite VIII	Yt(3)	6491, 6199(7), 5743(2).

Calcite IX	Mn(15)	6544, 6502, 6462(4), 6427, 6360(1), 6288(9), 6204(3), 6132, 6095(8), 5979(7), 5852(5), 5793(4), 5753(4), 5690(1), 5631.
Calcite IX	Yt(2)	6053, 5928(9).

Calcite X	Mn(19)	6545(4), 6464, 6426(7), 6360(1), 6225(7), 6201(3), 6159(8), 6129(31), 6099(8), 6048(6), 5980(77), 5973(4), 5909(10), 5794, 5752(4), 5680(2), 5630(1), 5575(4), 5523(5).
Calcite X	Dy(2)	6275, 5844(2).

Calcite XI	Mn(13)	6503(2), 6427, 6292(3), 6228(7), 6159(8), 6097(8), 6047(6), 5977, 5896, 5854(5), 5755(4), 5693(1), 5631.
Calcite XI	Dy(5)	6422, 6348, 6001, 5934(6), 5809(11).

Calcite XII	Mn(10)	6359(61), 6202(3), 6157(8), 6098, 5977, 5910, 5795(4), 5741, 5680(2), 5621(18).
Calcite XII	Sa(6)	6533(4), 6444(6), 6269, 6120(18), 6039(41), 5841.

Substance	Active Agents	Bands recognized

Crystalline Limestone I	Dy(11)	6100(1), 6001, 5907(5), 5873, 5810(1), 5780, 5749(50), 5720, 5690(1), 5660(1), 5632.
Crystalline Limestone I	Mn(7)	6048(6), 5978(7), 5895(6), 5855, 5752(4), 5559, 5430(2).
Red Band	Tl(4)	5951(48), 5884(7), 5711, 5602(0).
Blue Band	Dy(7)	4970, 4944(7); 4925, 4900(3), 4885(2), 4838(9), 4798(6),
	Mn(2)	5005, 4885(3).

Crystalline Limestone II	Mn(8)	5896, 5858(5), 5834(1), 5794; 5740(1), 5693(1), 5631, 5616(8).
	Dy(6)	5998(01), 5811, 5779(0), 5722(0), 5661, 5603.
	Tl(2)	5947(8), 5657(5).

Old Lime	Mn(12)	6361, 6288(9), 6228(7), 6158, 6099(8), 6048(6), 5974, 5911(0), 5752(4), 5691, 5628(1), 5574.
Old Lime	Dy(2)	5845(2), 5812(1).

Aragonite I	Mn(17)	6227, 6157(8), 6100(98), 6029(931), 5974, 5910, 5893(6), 5857(5), 5831, 5794, 5754, 5741, 5682, 5632(1), 5560(59), 5470, 5423.
Aragonite I	Sr(3)	5961(59), 5818(6), 5504(6).

Aragonite II	Sr(32)	5771(0), 5718(9), 5680, 5636, 5610, 5576(5), 5550, 5540, 5509(8), 5472, 5440(39), 5406, 5386(5), 5374(3), 5347(6), 5340(1), 5308(7), 5265(8), 5245(6), 5230(1), 5193, 5186(5), 5154(5), 5125, 5096, 5084, 5050(49), 5039(8), 5014, 5009(10), 4980, 4954.
Aragonite II	Cu(2)	5485, 5435.

Dolomite I	Dy(15)	6001, 5933(6), 5873, 5750, 5662(1), 5634(2), 5601(3), 5547, 5518(9), 5410, 5383(4), 5332, 5305(6), 5255, 5205.
Dolomite I	Mn(9)	5971(4), 5894(6), 5829(31), 5792(4), 5682, 5572(4), 5487(8), 5469(0), 5421(3).

Dolomite II	Mn(16)	6542(4), 6462(4), 6369, 6293, 6227, 6160(58), 6100(98), 5973(4), 5894(6), 5831, 5796(4), 5739(1), 5682, 5628(1), 5574, 5523(5).
Dolomite II	Yt(1)	6054(3).

Magnesite	Mn(10)	6543(4), 6461(4), 6290(3), 6206(3), 6131, 6046, 5979(7), 5910, 5855, 5794.
Magnesite	Dy(3)	6384(5), 6068, 5842.

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