Abstract

In the analysis of As ii, the usual Slater–Condon treatment was found unsatisfactory for the multiconfiguration group 4s4p3–4p4d–4p5d–4p6d–4p7s. It was found that when LS-dependent parameters were introduced there was a substantial improvement of the agreement between experimental and calculated energy levels and for the Landé g factors as well. We carried out Hartree–Fock (HF) solutions for each term of this multiconfiguration and obtained convincing evidence of the necessity for LS-dependent parameters. In N ii, P ii, Sb 1i, and Bi ii, we found the same pattern to hold in the HF solutions for the sp3 and the corresponding first three pd configurations.

© 1972 Optical Society of America

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