The Spectra of Argon, Krypton, and Xenon between 1.2 and 2.2 Microns*

W. R. Sittner; E. R. Peck

doi:10.1364/JOSA.39.000474

The Spectra of Argon, Krypton, and Xenon between 1.2 and 2.2 Microns

W. R. Sittner and E. R. Peck

Journal of the Optical Society of America
Vol. 39,
Issue 6,
pp. 474-477
(1949)
•https://doi.org/10.1364/JOSA.39.000474

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W. R. Sittner and E. R. Peck, "The Spectra of Argon, Krypton, and Xenon between 1.2 and 2.2 Microns*," J. Opt. Soc. Am. 39, 474-477 (1949)

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History
- Original Manuscript: February 28, 1949
- Published: June 1, 1949

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Abstract

The spectrum of argon, krypton, and xenon excited by a repetitive condenser discharge method has been studied in the near infra-red region. The use of this method of excitation and a large infra-red spectrograph using a lead sulfide detector reveals about 170 new lines in these gases. About three-fourths of the lines are classified by known terms of the normal atom.

Some anomalies of spectra excited by the repetitive condenser discharge method are mentioned.

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ν°obs.	Transition	ν°calc.	Δν°	I
cm⁻¹
8718.00	2p₇–3s₁″	8717.85	0.15	30	5
02.20	1S₂–2p₁₀	8702.20	0	40	4
8633.05	3d₄–4W	8632.91	+0.14	10	5
00.81				4
8567.56	2p₆–3s₁″	8567.56	0	50	4
53.84	2p₇–3s₁″ ″	8553.74	0.10	10	5
30.29	2p₈–3d₂	8530.29	0	20	4
20.33	3d₆–4X	8520.59	−0.26	20	5
8412.43	3d₅–4Y	8411.85	0.58	20	5
03.22	2p₆–3S₁″ ″	8403.45	0.23	10	5
8370.63	3d₅–4X	8370.49	0.14	50	5
12.85	2p₅–3s₁′	8312.57	0.28	20	5
8254.06	2p₉–3d₁′	8254.06	0	60	5
35.22	2p₄–3s,	8235.15	0.07	40	5
27.33	3d₁″–4W	18227.32	10.01	30	5
8099.40	2p₈–3d₁′	8099.49	−0.09	50	5
90.87	3d₃–4Y	8090.87	0	50	5
73.76				5
60.44	2p₇–3d₂	8060.36	0.08	60	3
49.95	3d₃–4X	8049.51	0.44	30	5
37.02	2p₁₀–3d₃	8037.00	0.02	60	3
25.83	2p₈–2s₄	8025.82	0.01	50	5
05.68	2p₉–2s₅	8005.65	0.03	60	4
7962.87	2p₉–3d₁″	7963.28	−0.41	10	5
36.60	3d₁′–4W	7936.54	−0.06	7
20.09	2p₅–2s₂	7920.76	−0.67	7	5
09.21	2p₆–3d₂	7910.07	−0.86	2
7870.46	2p₂–3s₁′	7870.44	0.02	50	3
50.91	2p₈–2s₅	7851.08	−0.17	33	5
43.09	2p₄–2s₂	7843.34	−0.25	30	5
08.75	2p₈–3d₁″	7808.71	0.04	60	3
7729.26	2p₄–2s₃	7729.85	−0.59	40	5
15.92	2p₁₀–3d₅	7716.02	−0.10	60	3
7684.99	2p₃–2s₂	7685.35	−0.36	50	3
73.28				2
7565.11	2p₁₀–3d₆	7565.92	−0.81	50
57.49	2p₉–3d₄	7557.69	−0.20	50	3
55.78	2p₇–2s₄	7555.89	−0.11	39
7532.27				60	3
15.34				5
09.41	2p₄–3s₁″ ″	7509.29	0.12	60	3
7499.67	2p₄–7s₁″	7498.94	0.73	30
79.06	2p₆–3d₁′	7479.27	−0.21	60	3
56.92				50
05.45	2p₆–2s₄	7405.60	−0.15	20
03.21	2p₈–3d₄	7403.12	0.09	60	3
7380.74				4
64.47	2p₂–2s₃	7365.14	−0.67	20
51.02	2p₃–3s₁″ ″	7351.30	−0.28	40
38.74	2p₇–3d₁″	7338.78	−0.04	50	3
08.83	2p₂–3s₁″	7308.69	0.14	50	3
7287.54	2p₉–3d₄′	7287.60	−0.06	60	3
29.85	2p₆–2s₅	7230.86	−1.01	30
08.92	3d₄–4Y	7209.46	−0.54	2
7187.34	2p₆–3d₁″	7188.49	−1.15	50
44.70	2p₂–3s₁″ ″	7144.58	0.12	40
7093.33	2p₅–3d₂	7093.33	0	50	3
15.82	2p₄–3d₂	7015.91	−0.09	20
12.16				40
6849.14	3s₁″–4Z	6849.39	−0.25	30
31.49	4d₅–6Z	6831.81	−0.32	40
23.98				20
03.73	3d₁″–4Y	6803.87	−0.14	5
6782.65	2p₆–3d₄	6782.90	−0.25	5
60.89	2s₅–4Y	6761.50	−0.61	1
21.67				1
6644.31	2p₁–3s₁′	6644.23	0.08	40
6588.82	2p₅–2s₄	6588.86	−0.04	20
47.05				4
33.62				20
21.73	2p₈–3d₃	6521.71	0.02	6
13.24	3d₁′–4Y	6513.09	0.15	10
11.51	2p₄–2s₄	6511.44	0.07	10
6490.84				8
6288.42	3s₁′–4Z	6287.64	0.78	40
52.32	2p₁–2s₂	6252.42	−0.10	30
6178.12	2p₃–2s₅	6178.71	−0.59	2
6092.12				7
82.33	3d₂–4Y	6082.29	0.04	10
82.33	2p₁–3s₁″	6082.48	−0.15
52.55	2p₇–3d₃	6051.78	0.77	10
41.06	3d₂–4X	6040.93	0.13	6
5971.86	2p₂–2s₅	5971.99	−0.13	6
01.59	2p₆–3d₃	5901.49	0.10	50	3
5808 35				2
5580.55	2p₇–3d₆	5580.70	−0.15	10
5580.55	2p₆–3d₅	5580.51	0.04	10

ν°obs.	Transition	ν°calc	Δν°	I
8277.96	3d₃–4Z	8277.62	0.34	50	5
50.09	3d₄′–4W	8250.09	0	40	4
45.82	1s₂–2p₅	8246.15	−0.33	5	5
8191.13	3d₄′–4U	8191.43	−0.30	70
13.83				30
7821.12	3d₄–4W	7821.17	−0.05	40
7794.70	3d₄–4Y	7794.99	−0.29	10
72.41	1s₃–2p₇	7772.77	−0.36	10
62.56	3d₄–4U	7762.51	0.05	50	4
41.05				3
7698.32	2p₁₀–3d₁″	7699.01	−0.69	10
76.47				50
7586.66	2p₈–2s₄	7586.73	−0.07	50	4
78.37				46
66.35				4
49.90	2p₄–3s₁′	7550.43	−0.53	50
7494.87				30
7154.11	3d₁″–4Y	7153.82	0.29	10
6968.53	3d₁′–4W	6968.17	0.36	50
6941.89	2p₂–2s₂	6942.14	−0.25	30	4
6929.97	2p₇–2s₄	6929.72	0.25	50
6909.74	3d₁′–4U	6909.51	0.23	40
6886.32	3d₁′–4Z	6885.97	0.35	5
6796.29				4
6772.03	2p₈–3d₁′	6771.97	0.06	60	4
6770.39	2p₆–2s₄	6770.77	−0.38	60
6681.56	2p₇–3d₂	6681.29	0.27	50
6661.74	2p₇–2s₅	6662.55	−0.81	30
6587.65				20
6573.35	2p₉–3d₁″	6573.12	0.23	20
6560.05	2p₈–3d₁″	6560.14	−0.09	60
6548.75				3
6529.86				3
6522.53	2p₆–3d₂	6522.34	0.19	5
6519.19	2p₁₀–3d₃	6519.19	0	60	4
6503.09	2p₆–2s₅	6503.60	−0.51	50
6460.84	2s₂–2p₈	6460.67	0.17	30
6394.20	2s₅–4Y	6394.40	−0.20	3
6375.59	3d₂–4Y	6375.66	−0.07	40
6319.40	3d₂–4X	6318.84	0.56	20	4
6319.40	3d₂–4Z	6319.64	−0.24
6290.53	2p₁–3s₁′	6291.27	−0.74	7
6227.31	3d₅–3p₇	6228.44	−1.13	6
6127.23	2s₄–4Y	6127.23	0	2
6032.59	2p₁–2s₂	6032.24	0.35	2
5982.33				50
5979.64				2
5976.46	1s₃–2p₁₀	5976.89	−0.43	20
5965.93				1
5956.05	2p₆–3d₁′	5956.01	0.04	60
5931.86	2p₉–3d₄	5931.95	−0.09	40	4
5928.73				1
5926.33				1
5918.95	2p₈–3d₄	5918.97	−0.02	60
5916.75	2p₁₀–3d₅	5916.53	0.22	50
5908.98				1
5903.06	2p₇–3d₁″	5903.13	−0.07	60
5856.69				1
5846.91	2p₄–3s₁″	5846.77	0.14	40
5770.12				1
5756.36	2p₂–3s₁″ ′	5756.26	0.10	50	4
5744.15	2p₆–3d₁″	5744.18	−0.03	3
5674.22	3d₃–3p₆	5674.92	−0.70	1
5602.97	2p₁₀–3d₆	5602.99	−0.02	40	4
5553.34	2p₅–3d₂	5552.82	0.52	50
5523.50	2p₃–3s₁″	5523.54	−0.04	2
5502.93	2p₉–3d₄′	5503.03	−0.10	60	4
5497.57	2p₂–3s₁″	5497.52	0.05	4
5380.45	2p₈–3d₃	5380.32	0.13	3
5346.76	2p₃–3s₁″ ″	5347.25	−0.49	10
5321.61	2p₂–3s₁″ ″	5321.23	0.38	7	4
5321.61	1s₂–2p₁₀	5321.80	−0.19
5317.88	3d₄′–3p₉	5318.22	−0.34	3
5317.17				3
4896.06	3p₆–5d₂	4896.17	−0.11	1
4566.99				8

ν°obs.	Transition	ν°calc.	Δν°	I
9683.54				20
9175.74	3d₅–2p₃	9175.72	0.02	60	5
8839.48	3d₃–2p₃	8839.60	0.12	2	5
8758.06	3d₅–3p₇	8757.92	0.14	6	5
8699.94	3d₅–3p₆	8699.86	0.08	2	5
8607.80	3d₆–2p₄	8607.849	−0.05	30	5
8514.02	3d₁′–4W	8513.84	0.18	70	5
8476.84	3d₁′–4U	8476.89	−0.05	50	5
8431.47	3d₁′–4Z	8431.34	0.13	50	5
8418.53	3d₁′–4Y	8419.25	−0.72	5	5
8392.50	3d₅–2p₄	8392.49	0.01	8	5
8363.26	3d₃–3p₆	8363.74	−0.48	6	5
8272.59	3d₄′–3p₈	8272.57	0.02	15	5
8192.10	3d₄–2p₃	8191.90	0.20	5
8170.88	2p₁₀–2s₄	8170.88	0	50	5
8155.85	3d₆–3p₁₀	8155.85	0	8	5
8145.82	3d₃–3p₈	8146.45	−0.63	2
8028.32	3d₃–3p₉	8028.92	−0.60	2
7940.70	3d₅–3p₁₀	7940.49	0.21	20
7919.30	2p₁₀–2s₅	7919.66	0.36	100	5
7320.19	2p₉–2S₄	7320.23	−0.04	70
7068.95	2p₉–2s₅	7069.01	−0.06	50
7020.18	3d₂–4V	7020.11	0.07	60
6959.46	3d₂–4Y	6959.50	−0.04	50
6949.89	3d₂–4X	6949.83	0.06	3
6819.02	3d₁″–3p₇	6818.96	0.06	5
6785.70	2p₈–2s₅	6785.75	−0.05	200
6484.16	3p₇–2s₄	6483.99	0.17	70
6227.44	2p₆–2s₄	6227.56	−0.12	20
5976.05	2p₆–2s₅	5976.34	−0.29	20
5770.24	2p₉–3d₂	5770.17	0.07	5
5320.79	2p₅–2s₄	5321.06	−0.27	3
5320.06				3
5268.57				3
5267.49				3
5135.58				4
4936.37				2
4933.96	2p₇–3d₂	4933.93	.03	6
4749.56				2

ν°obs.	Transition	ν°calc.	Δν°	I
cm⁻¹
8718.00	2p₇–3s₁″	8717.85	0.15	30	5
02.20	1S₂–2p₁₀	8702.20	0	40	4
8633.05	3d₄–4W	8632.91	+0.14	10	5
00.81				4
8567.56	2p₆–3s₁″	8567.56	0	50	4
53.84	2p₇–3s₁″ ″	8553.74	0.10	10	5
30.29	2p₈–3d₂	8530.29	0	20	4
20.33	3d₆–4X	8520.59	−0.26	20	5
8412.43	3d₅–4Y	8411.85	0.58	20	5
03.22	2p₆–3S₁″ ″	8403.45	0.23	10	5
8370.63	3d₅–4X	8370.49	0.14	50	5
12.85	2p₅–3s₁′	8312.57	0.28	20	5
8254.06	2p₉–3d₁′	8254.06	0	60	5
35.22	2p₄–3s,	8235.15	0.07	40	5
27.33	3d₁″–4W	18227.32	10.01	30	5
8099.40	2p₈–3d₁′	8099.49	−0.09	50	5
90.87	3d₃–4Y	8090.87	0	50	5
73.76				5
60.44	2p₇–3d₂	8060.36	0.08	60	3
49.95	3d₃–4X	8049.51	0.44	30	5
37.02	2p₁₀–3d₃	8037.00	0.02	60	3
25.83	2p₈–2s₄	8025.82	0.01	50	5
05.68	2p₉–2s₅	8005.65	0.03	60	4
7962.87	2p₉–3d₁″	7963.28	−0.41	10	5
36.60	3d₁′–4W	7936.54	−0.06	7
20.09	2p₅–2s₂	7920.76	−0.67	7	5
09.21	2p₆–3d₂	7910.07	−0.86	2
7870.46	2p₂–3s₁′	7870.44	0.02	50	3
50.91	2p₈–2s₅	7851.08	−0.17	33	5
43.09	2p₄–2s₂	7843.34	−0.25	30	5
08.75	2p₈–3d₁″	7808.71	0.04	60	3
7729.26	2p₄–2s₃	7729.85	−0.59	40	5
15.92	2p₁₀–3d₅	7716.02	−0.10	60	3
7684.99	2p₃–2s₂	7685.35	−0.36	50	3
73.28				2
7565.11	2p₁₀–3d₆	7565.92	−0.81	50
57.49	2p₉–3d₄	7557.69	−0.20	50	3
55.78	2p₇–2s₄	7555.89	−0.11	39
7532.27				60	3
15.34				5
09.41	2p₄–3s₁″ ″	7509.29	0.12	60	3
7499.67	2p₄–7s₁″	7498.94	0.73	30
79.06	2p₆–3d₁′	7479.27	−0.21	60	3
56.92				50
05.45	2p₆–2s₄	7405.60	−0.15	20
03.21	2p₈–3d₄	7403.12	0.09	60	3
7380.74				4
64.47	2p₂–2s₃	7365.14	−0.67	20
51.02	2p₃–3s₁″ ″	7351.30	−0.28	40
38.74	2p₇–3d₁″	7338.78	−0.04	50	3
08.83	2p₂–3s₁″	7308.69	0.14	50	3
7287.54	2p₉–3d₄′	7287.60	−0.06	60	3
29.85	2p₆–2s₅	7230.86	−1.01	30
08.92	3d₄–4Y	7209.46	−0.54	2
7187.34	2p₆–3d₁″	7188.49	−1.15	50
44.70	2p₂–3s₁″ ″	7144.58	0.12	40
7093.33	2p₅–3d₂	7093.33	0	50	3
15.82	2p₄–3d₂	7015.91	−0.09	20
12.16				40
6849.14	3s₁″–4Z	6849.39	−0.25	30
31.49	4d₅–6Z	6831.81	−0.32	40
23.98				20
03.73	3d₁″–4Y	6803.87	−0.14	5
6782.65	2p₆–3d₄	6782.90	−0.25	5
60.89	2s₅–4Y	6761.50	−0.61	1
21.67				1
6644.31	2p₁–3s₁′	6644.23	0.08	40
6588.82	2p₅–2s₄	6588.86	−0.04	20
47.05				4
33.62				20
21.73	2p₈–3d₃	6521.71	0.02	6
13.24	3d₁′–4Y	6513.09	0.15	10
11.51	2p₄–2s₄	6511.44	0.07	10
6490.84				8
6288.42	3s₁′–4Z	6287.64	0.78	40
52.32	2p₁–2s₂	6252.42	−0.10	30
6178.12	2p₃–2s₅	6178.71	−0.59	2
6092.12				7
82.33	3d₂–4Y	6082.29	0.04	10
82.33	2p₁–3s₁″	6082.48	−0.15
52.55	2p₇–3d₃	6051.78	0.77	10
41.06	3d₂–4X	6040.93	0.13	6
5971.86	2p₂–2s₅	5971.99	−0.13	6
01.59	2p₆–3d₃	5901.49	0.10	50	3
5808 35				2
5580.55	2p₇–3d₆	5580.70	−0.15	10
5580.55	2p₆–3d₅	5580.51	0.04	10

ν°obs.	Transition	ν°calc	Δν°	I
8277.96	3d₃–4Z	8277.62	0.34	50	5
50.09	3d₄′–4W	8250.09	0	40	4
45.82	1s₂–2p₅	8246.15	−0.33	5	5
8191.13	3d₄′–4U	8191.43	−0.30	70
13.83				30
7821.12	3d₄–4W	7821.17	−0.05	40
7794.70	3d₄–4Y	7794.99	−0.29	10
72.41	1s₃–2p₇	7772.77	−0.36	10
62.56	3d₄–4U	7762.51	0.05	50	4
41.05				3
7698.32	2p₁₀–3d₁″	7699.01	−0.69	10
76.47				50
7586.66	2p₈–2s₄	7586.73	−0.07	50	4
78.37				46
66.35				4
49.90	2p₄–3s₁′	7550.43	−0.53	50
7494.87				30
7154.11	3d₁″–4Y	7153.82	0.29	10
6968.53	3d₁′–4W	6968.17	0.36	50
6941.89	2p₂–2s₂	6942.14	−0.25	30	4
6929.97	2p₇–2s₄	6929.72	0.25	50
6909.74	3d₁′–4U	6909.51	0.23	40
6886.32	3d₁′–4Z	6885.97	0.35	5
6796.29				4
6772.03	2p₈–3d₁′	6771.97	0.06	60	4
6770.39	2p₆–2s₄	6770.77	−0.38	60
6681.56	2p₇–3d₂	6681.29	0.27	50
6661.74	2p₇–2s₅	6662.55	−0.81	30
6587.65				20
6573.35	2p₉–3d₁″	6573.12	0.23	20
6560.05	2p₈–3d₁″	6560.14	−0.09	60
6548.75				3
6529.86				3
6522.53	2p₆–3d₂	6522.34	0.19	5
6519.19	2p₁₀–3d₃	6519.19	0	60	4
6503.09	2p₆–2s₅	6503.60	−0.51	50
6460.84	2s₂–2p₈	6460.67	0.17	30
6394.20	2s₅–4Y	6394.40	−0.20	3
6375.59	3d₂–4Y	6375.66	−0.07	40
6319.40	3d₂–4X	6318.84	0.56	20	4
6319.40	3d₂–4Z	6319.64	−0.24
6290.53	2p₁–3s₁′	6291.27	−0.74	7
6227.31	3d₅–3p₇	6228.44	−1.13	6
6127.23	2s₄–4Y	6127.23	0	2
6032.59	2p₁–2s₂	6032.24	0.35	2
5982.33				50
5979.64				2
5976.46	1s₃–2p₁₀	5976.89	−0.43	20
5965.93				1
5956.05	2p₆–3d₁′	5956.01	0.04	60
5931.86	2p₉–3d₄	5931.95	−0.09	40	4
5928.73				1
5926.33				1
5918.95	2p₈–3d₄	5918.97	−0.02	60
5916.75	2p₁₀–3d₅	5916.53	0.22	50
5908.98				1
5903.06	2p₇–3d₁″	5903.13	−0.07	60
5856.69				1
5846.91	2p₄–3s₁″	5846.77	0.14	40
5770.12				1
5756.36	2p₂–3s₁″ ′	5756.26	0.10	50	4
5744.15	2p₆–3d₁″	5744.18	−0.03	3
5674.22	3d₃–3p₆	5674.92	−0.70	1
5602.97	2p₁₀–3d₆	5602.99	−0.02	40	4
5553.34	2p₅–3d₂	5552.82	0.52	50
5523.50	2p₃–3s₁″	5523.54	−0.04	2
5502.93	2p₉–3d₄′	5503.03	−0.10	60	4
5497.57	2p₂–3s₁″	5497.52	0.05	4
5380.45	2p₈–3d₃	5380.32	0.13	3
5346.76	2p₃–3s₁″ ″	5347.25	−0.49	10
5321.61	2p₂–3s₁″ ″	5321.23	0.38	7	4
5321.61	1s₂–2p₁₀	5321.80	−0.19
5317.88	3d₄′–3p₉	5318.22	−0.34	3
5317.17				3
4896.06	3p₆–5d₂	4896.17	−0.11	1
4566.99				8

Abstract

References

Cited By

Figures (1)

Tables (3)

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