For strongly absorbing bands measured with a Fourier transform infrared (FT-IR) spectrometer, the effects of a nonlinear detector response must be eliminated before Beer's law linearity can be achieved. An empirical method for greatly reducing the effect of detector nonlinearity on FT-IR Beer's law spectra measured by using an FT-IR spectrometer equipped with a mercury-cadmium-telluride (MCT) detector is investigated. This first-order analytical function has been applied to correct nonlinear vapor-phase spectra and statistically evaluated for validity for spectral regions above the detector cutoff. In addition, a series of second-order functions has been evaluated to investigate the possibility that the transmittance scale is slightly nonlinear even after the first-order correction has been applied. Any improvement caused by the second-order functions was not statistically significant.

PDF Article

Cited By

You do not have subscription access to this journal. Cited by links are available to subscribers only. You may subscribe either as an OSA member, or as an authorized user of your institution.

Contact your librarian or system administrator
Login to access OSA Member Subscription