Abstract

The reaction behavior of the complex [Cr<sub>3</sub>(μ<sub>3</sub>-O)(μ-O<sub>2</sub>CH)<sub>6</sub>-(H<sub>2</sub>O)<sub>2</sub>(O<sub>2</sub>CH)]·<i>x</i>H<sub>2</sub>O [shown as (Cr<sub>3</sub>FF)] has been investigated in the system of acetylene with water vapor by means of <i>in situ</i> IR and TG analyses. It has been observed that some active fragments obtained by the loss of part of the ligands of (Cr<sub>3</sub>FF) demonstrated activity for the additional reaction of acetylene with water or hydrogen, forming either acetaldehyde or ethylene. On the basis of the study of the thermo-decomposition process, as well as the FAB-MS data, the nature of these active fragments has been elucidated.

PDF Article

Cited By

You do not have subscription access to this journal. Cited by links are available to subscribers only. You may subscribe either as an OSA member, or as an authorized user of your institution.

Contact your librarian or system administrator
or
Login to access OSA Member Subscription