Abstract

The development of dispersive instrumentation for the measurement of vibrational circular dichroism (VCD) with a lower frequency limit of ∼650 cm<sup>−1</sup> is reported. VCD spectra of 3-methylcyclohexanone, α-pinene, and 3-bromocamphor in the frequency range of 800 to 650 cm<sup>−1</sup> are presented to illustrate instrumental performance. The spectra obtained are superior to earlier spectra obtained with the use of a Fourier transform spectrometer.

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