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Nonlinear Absorption in the Blue: Photophysics of a New Ruthenium-Based Phthalocyanine

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Abstract

The photophysics of novel ruthenium-based phthalocyanines are reported. These materials undergo rapid intersystem crossing with yield ~1. Large excited-state-absorption cross-sections with intensity-independent kinetics demonstrate their potential as effective nonlinear absorber in the blue spectral region.

© 2010 Optical Society of America

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